< VirtualHost *:80>
    ServerName wargot.local
    ServerAlias www.wargot.local
    ServerAdmin [email protected]
    DocumentRoot /home/wargot/www/cms.local/web

    ErrorLog ${APACHE_LOG_DIR}/error.log
    CustomLog ${APACHE_LOG_DIR}/access.log combined
    < Directory /home/wargot/www/cms.local/web/>
        Options Indexes FollowSymLinks MultiViews
        AllowOverride None
        Order allow,deny
        allow from all
        < IfModule mod_rewrite.c>
            RewriteEngine On
            RewriteCond %{REQUEST_FILENAME} !-f
            RewriteRule ^(.*)$ /app.php [QSA,L]
        < /IfModule>
    < /Directory>
< /VirtualHost>

У меня там лишние пробельчики в блоках VirtualHost, Directory, IfModule, не забудьте удалить